Tetra­aqua­bis{μ(2)-2,7-bis­[(2,6-diisopropyl­phen­yl)imino­meth­yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis­(trimethyl­phosphine oxide)tetra­nickel(II)–trimethyl­phosphine oxide–diethyl ether–water (1/2/2/2)

The title complex, [Ni(4)(C(36)H(40)N(2)O(2))(2)(OH)(4)(C(3)H(9)OP)(2)(H(2)O)(4)]·2C(4)H(10)O·2C(3)H(9)OP·2H(2)O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each Ni(II...

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Detalles Bibliográficos
Autores principales: Delferro, Massimiliano, Weberski, Michael P., Rodriguez, Brandon A., Marks, Tobin J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983651/
https://www.ncbi.nlm.nih.gov/pubmed/21580211
http://dx.doi.org/10.1107/S1600536810003697
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author Delferro, Massimiliano
Weberski, Michael P.
Rodriguez, Brandon A.
Marks, Tobin J.
author_facet Delferro, Massimiliano
Weberski, Michael P.
Rodriguez, Brandon A.
Marks, Tobin J.
author_sort Delferro, Massimiliano
collection PubMed
description The title complex, [Ni(4)(C(36)H(40)N(2)O(2))(2)(OH)(4)(C(3)H(9)OP)(2)(H(2)O)(4)]·2C(4)H(10)O·2C(3)H(9)OP·2H(2)O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each Ni(II) atom adopts a distorted octa­hedral geometry.
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spelling pubmed-29836512010-12-30 Tetra­aqua­bis{μ(2)-2,7-bis­[(2,6-diisopropyl­phen­yl)imino­meth­yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis­(trimethyl­phosphine oxide)tetra­nickel(II)–trimethyl­phosphine oxide–diethyl ether–water (1/2/2/2) Delferro, Massimiliano Weberski, Michael P. Rodriguez, Brandon A. Marks, Tobin J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(4)(C(36)H(40)N(2)O(2))(2)(OH)(4)(C(3)H(9)OP)(2)(H(2)O)(4)]·2C(4)H(10)O·2C(3)H(9)OP·2H(2)O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each Ni(II) atom adopts a distorted octa­hedral geometry. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983651/ /pubmed/21580211 http://dx.doi.org/10.1107/S1600536810003697 Text en © Delferro et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Delferro, Massimiliano
Weberski, Michael P.
Rodriguez, Brandon A.
Marks, Tobin J.
Tetra­aqua­bis{μ(2)-2,7-bis­[(2,6-diisopropyl­phen­yl)imino­meth­yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis­(trimethyl­phosphine oxide)tetra­nickel(II)–trimethyl­phosphine oxide–diethyl ether–water (1/2/2/2)
title Tetra­aqua­bis{μ(2)-2,7-bis­[(2,6-diisopropyl­phen­yl)imino­meth­yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis­(trimethyl­phosphine oxide)tetra­nickel(II)–trimethyl­phosphine oxide–diethyl ether–water (1/2/2/2)
title_full Tetra­aqua­bis{μ(2)-2,7-bis­[(2,6-diisopropyl­phen­yl)imino­meth­yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis­(trimethyl­phosphine oxide)tetra­nickel(II)–trimethyl­phosphine oxide–diethyl ether–water (1/2/2/2)
title_fullStr Tetra­aqua­bis{μ(2)-2,7-bis­[(2,6-diisopropyl­phen­yl)imino­meth­yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis­(trimethyl­phosphine oxide)tetra­nickel(II)–trimethyl­phosphine oxide–diethyl ether–water (1/2/2/2)
title_full_unstemmed Tetra­aqua­bis{μ(2)-2,7-bis­[(2,6-diisopropyl­phen­yl)imino­meth­yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis­(trimethyl­phosphine oxide)tetra­nickel(II)–trimethyl­phosphine oxide–diethyl ether–water (1/2/2/2)
title_short Tetra­aqua­bis{μ(2)-2,7-bis­[(2,6-diisopropyl­phen­yl)imino­meth­yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis­(trimethyl­phosphine oxide)tetra­nickel(II)–trimethyl­phosphine oxide–diethyl ether–water (1/2/2/2)
title_sort tetra­aqua­bis{μ(2)-2,7-bis­[(2,6-diisopropyl­phen­yl)imino­meth­yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis­(trimethyl­phosphine oxide)tetra­nickel(ii)–trimethyl­phosphine oxide–diethyl ether–water (1/2/2/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983651/
https://www.ncbi.nlm.nih.gov/pubmed/21580211
http://dx.doi.org/10.1107/S1600536810003697
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AT weberskimichaelp tetraaquabism227bis26diisopropylphenyliminomethylnaphthalene18diolatodim3hydroxidodim2hydroxidobistrimethylphosphineoxidetetranickeliitrimethylphosphineoxidediethyletherwater1222
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