(Z)-Ethyl 3-(2,6-diisopropylanilino)but-2-enoate
The title compound, C(18)H(27)NO(2), crystallizes as the enamine form with Z geometry. The β-enaminoester fragment forms a dihedral angle of 87.5 (1)° with the isopropylphenyl frame. The structure exhibits an intramolecular N—H⋯O hydrogen bond. In addition, in the crystal, molecules are linked b...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983729/ https://www.ncbi.nlm.nih.gov/pubmed/21580278 http://dx.doi.org/10.1107/S1600536810003260 |
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author | Amézquita-Valencia, Manuel Hernández-Ortega, Simón Suárez-Ortiz, G. Alejandra Cabrera, Armando |
author_facet | Amézquita-Valencia, Manuel Hernández-Ortega, Simón Suárez-Ortiz, G. Alejandra Cabrera, Armando |
author_sort | Amézquita-Valencia, Manuel |
collection | PubMed |
description | The title compound, C(18)H(27)NO(2), crystallizes as the enamine form with Z geometry. The β-enaminoester fragment forms a dihedral angle of 87.5 (1)° with the isopropylphenyl frame. The structure exhibits an intramolecular N—H⋯O hydrogen bond. In addition, in the crystal, molecules are linked by a centrosymmetric intermolecular N—H⋯O hydrogen bond. |
format | Text |
id | pubmed-2983729 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29837292010-12-30 (Z)-Ethyl 3-(2,6-diisopropylanilino)but-2-enoate Amézquita-Valencia, Manuel Hernández-Ortega, Simón Suárez-Ortiz, G. Alejandra Cabrera, Armando Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(27)NO(2), crystallizes as the enamine form with Z geometry. The β-enaminoester fragment forms a dihedral angle of 87.5 (1)° with the isopropylphenyl frame. The structure exhibits an intramolecular N—H⋯O hydrogen bond. In addition, in the crystal, molecules are linked by a centrosymmetric intermolecular N—H⋯O hydrogen bond. International Union of Crystallography 2010-02-03 /pmc/articles/PMC2983729/ /pubmed/21580278 http://dx.doi.org/10.1107/S1600536810003260 Text en © Amézquita-Valencia et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Amézquita-Valencia, Manuel Hernández-Ortega, Simón Suárez-Ortiz, G. Alejandra Cabrera, Armando (Z)-Ethyl 3-(2,6-diisopropylanilino)but-2-enoate |
title | (Z)-Ethyl 3-(2,6-diisopropylanilino)but-2-enoate |
title_full | (Z)-Ethyl 3-(2,6-diisopropylanilino)but-2-enoate |
title_fullStr | (Z)-Ethyl 3-(2,6-diisopropylanilino)but-2-enoate |
title_full_unstemmed | (Z)-Ethyl 3-(2,6-diisopropylanilino)but-2-enoate |
title_short | (Z)-Ethyl 3-(2,6-diisopropylanilino)but-2-enoate |
title_sort | (z)-ethyl 3-(2,6-diisopropylanilino)but-2-enoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983729/ https://www.ncbi.nlm.nih.gov/pubmed/21580278 http://dx.doi.org/10.1107/S1600536810003260 |
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