(Z)-Ethyl 3-(2,6-diisopropyl­anilino)but-2-enoate

The title compound, C(18)H(27)NO(2), crystallizes as the enamine form with Z geometry. The β-enamino­ester fragment forms a dihedral angle of 87.5 (1)° with the isopropyl­phenyl frame. The structure exhibits an intra­molecular N—H⋯O hydrogen bond. In addition, in the crystal, mol­ecules are linked b...

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Autores principales: Amézquita-Valencia, Manuel, Hernández-Ortega, Simón, Suárez-Ortiz, G. Alejandra, Cabrera, Armando
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983729/
https://www.ncbi.nlm.nih.gov/pubmed/21580278
http://dx.doi.org/10.1107/S1600536810003260
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author Amézquita-Valencia, Manuel
Hernández-Ortega, Simón
Suárez-Ortiz, G. Alejandra
Cabrera, Armando
author_facet Amézquita-Valencia, Manuel
Hernández-Ortega, Simón
Suárez-Ortiz, G. Alejandra
Cabrera, Armando
author_sort Amézquita-Valencia, Manuel
collection PubMed
description The title compound, C(18)H(27)NO(2), crystallizes as the enamine form with Z geometry. The β-enamino­ester fragment forms a dihedral angle of 87.5 (1)° with the isopropyl­phenyl frame. The structure exhibits an intra­molecular N—H⋯O hydrogen bond. In addition, in the crystal, mol­ecules are linked by a centrosymmetric inter­molecular N—H⋯O hydrogen bond.
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spelling pubmed-29837292010-12-30 (Z)-Ethyl 3-(2,6-diisopropyl­anilino)but-2-enoate Amézquita-Valencia, Manuel Hernández-Ortega, Simón Suárez-Ortiz, G. Alejandra Cabrera, Armando Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(27)NO(2), crystallizes as the enamine form with Z geometry. The β-enamino­ester fragment forms a dihedral angle of 87.5 (1)° with the isopropyl­phenyl frame. The structure exhibits an intra­molecular N—H⋯O hydrogen bond. In addition, in the crystal, mol­ecules are linked by a centrosymmetric inter­molecular N—H⋯O hydrogen bond. International Union of Crystallography 2010-02-03 /pmc/articles/PMC2983729/ /pubmed/21580278 http://dx.doi.org/10.1107/S1600536810003260 Text en © Amézquita-Valencia et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Amézquita-Valencia, Manuel
Hernández-Ortega, Simón
Suárez-Ortiz, G. Alejandra
Cabrera, Armando
(Z)-Ethyl 3-(2,6-diisopropyl­anilino)but-2-enoate
title (Z)-Ethyl 3-(2,6-diisopropyl­anilino)but-2-enoate
title_full (Z)-Ethyl 3-(2,6-diisopropyl­anilino)but-2-enoate
title_fullStr (Z)-Ethyl 3-(2,6-diisopropyl­anilino)but-2-enoate
title_full_unstemmed (Z)-Ethyl 3-(2,6-diisopropyl­anilino)but-2-enoate
title_short (Z)-Ethyl 3-(2,6-diisopropyl­anilino)but-2-enoate
title_sort (z)-ethyl 3-(2,6-diisopropyl­anilino)but-2-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983729/
https://www.ncbi.nlm.nih.gov/pubmed/21580278
http://dx.doi.org/10.1107/S1600536810003260
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