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(Disulfur dinitrido)triphenylantimony(V)
The title compound, [Sb(C(6)H(5))(3)(N(2)S(2))], contains a molecular entity that is very similar to that of the known polymorph of Sb(S(2)N(2))Ph(3) [Kunkel et al. (1997 ▶). Z. Naturforsch. Teil B, 52, 193–198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983911/ https://www.ncbi.nlm.nih.gov/pubmed/21580516 http://dx.doi.org/10.1107/S1600536810009487 |
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| author | Slawin, Alexandra M. Z. Waddell, Paul G. Woollins, J. Derek |
| author_facet | Slawin, Alexandra M. Z. Waddell, Paul G. Woollins, J. Derek |
| author_sort | Slawin, Alexandra M. Z. |
| collection | PubMed |
| description | The title compound, [Sb(C(6)H(5))(3)(N(2)S(2))], contains a molecular entity that is very similar to that of the known polymorph of Sb(S(2)N(2))Ph(3) [Kunkel et al. (1997 ▶). Z. Naturforsch. Teil B, 52, 193–198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S—N=S=N, consisting of one long S—N bond, an intermediate length N=S bond and a short S=N bond. |
| format | Text |
| id | pubmed-2983911 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29839112010-12-30 (Disulfur dinitrido)triphenylantimony(V) Slawin, Alexandra M. Z. Waddell, Paul G. Woollins, J. Derek Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sb(C(6)H(5))(3)(N(2)S(2))], contains a molecular entity that is very similar to that of the known polymorph of Sb(S(2)N(2))Ph(3) [Kunkel et al. (1997 ▶). Z. Naturforsch. Teil B, 52, 193–198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S—N=S=N, consisting of one long S—N bond, an intermediate length N=S bond and a short S=N bond. International Union of Crystallography 2010-03-17 /pmc/articles/PMC2983911/ /pubmed/21580516 http://dx.doi.org/10.1107/S1600536810009487 Text en © Slawin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Slawin, Alexandra M. Z. Waddell, Paul G. Woollins, J. Derek (Disulfur dinitrido)triphenylantimony(V) |
| title | (Disulfur dinitrido)triphenylantimony(V) |
| title_full | (Disulfur dinitrido)triphenylantimony(V) |
| title_fullStr | (Disulfur dinitrido)triphenylantimony(V) |
| title_full_unstemmed | (Disulfur dinitrido)triphenylantimony(V) |
| title_short | (Disulfur dinitrido)triphenylantimony(V) |
| title_sort | (disulfur dinitrido)triphenylantimony(v) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983911/ https://www.ncbi.nlm.nih.gov/pubmed/21580516 http://dx.doi.org/10.1107/S1600536810009487 |
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