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(Triphenylphosphine-κP)[1,1,1-tris(diphenylphosphinomethyl)ethane-κ(3) P,P′,P′′]copper(I) tetrafluoridoborate
In the title mononuclear Cu(I) complex, [Cu(C(18)H(15)P)(C(41)H(39)P(3))]BF(4), the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetrahedral geometry, the distortion arising from the steric hindrance of...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983927/ https://www.ncbi.nlm.nih.gov/pubmed/21580482 http://dx.doi.org/10.1107/S1600536810007312 |