(Triphenyl­phosphine-κP)[1,1,1-tris­(diphenyl­phosphinometh­yl)ethane-κ(3) P,P′,P′′]copper(I) tetra­fluoridoborate

In the title mononuclear Cu(I) complex, [Cu(C(18)H(15)P)(C(41)H(39)P(3))]BF(4), the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetra­hedral geometry, the distortion arising from the steric hindrance of...

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Detalles Bibliográficos
Autores principales: Yin, Qi, Gan, Xin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983927/
https://www.ncbi.nlm.nih.gov/pubmed/21580482
http://dx.doi.org/10.1107/S1600536810007312
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author Yin, Qi
Gan, Xin
author_facet Yin, Qi
Gan, Xin
author_sort Yin, Qi
collection PubMed
description In the title mononuclear Cu(I) complex, [Cu(C(18)H(15)P)(C(41)H(39)P(3))]BF(4), the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetra­hedral geometry, the distortion arising from the steric hindrance of the phenyl groups. The anion is disordered over two positions, with an occupancy ratio of 0.524 (17):0.476 (17). The cations and anions are closely packed in the crystal and are in h.c.p. arrangements.
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spelling pubmed-29839272010-12-30 (Triphenyl­phosphine-κP)[1,1,1-tris­(diphenyl­phosphinometh­yl)ethane-κ(3) P,P′,P′′]copper(I) tetra­fluoridoborate Yin, Qi Gan, Xin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear Cu(I) complex, [Cu(C(18)H(15)P)(C(41)H(39)P(3))]BF(4), the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetra­hedral geometry, the distortion arising from the steric hindrance of the phenyl groups. The anion is disordered over two positions, with an occupancy ratio of 0.524 (17):0.476 (17). The cations and anions are closely packed in the crystal and are in h.c.p. arrangements. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983927/ /pubmed/21580482 http://dx.doi.org/10.1107/S1600536810007312 Text en © Yin and Gan 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yin, Qi
Gan, Xin
(Triphenyl­phosphine-κP)[1,1,1-tris­(diphenyl­phosphinometh­yl)ethane-κ(3) P,P′,P′′]copper(I) tetra­fluoridoborate
title (Triphenyl­phosphine-κP)[1,1,1-tris­(diphenyl­phosphinometh­yl)ethane-κ(3) P,P′,P′′]copper(I) tetra­fluoridoborate
title_full (Triphenyl­phosphine-κP)[1,1,1-tris­(diphenyl­phosphinometh­yl)ethane-κ(3) P,P′,P′′]copper(I) tetra­fluoridoborate
title_fullStr (Triphenyl­phosphine-κP)[1,1,1-tris­(diphenyl­phosphinometh­yl)ethane-κ(3) P,P′,P′′]copper(I) tetra­fluoridoborate
title_full_unstemmed (Triphenyl­phosphine-κP)[1,1,1-tris­(diphenyl­phosphinometh­yl)ethane-κ(3) P,P′,P′′]copper(I) tetra­fluoridoborate
title_short (Triphenyl­phosphine-κP)[1,1,1-tris­(diphenyl­phosphinometh­yl)ethane-κ(3) P,P′,P′′]copper(I) tetra­fluoridoborate
title_sort (triphenyl­phosphine-κp)[1,1,1-tris­(diphenyl­phosphinometh­yl)ethane-κ(3) p,p′,p′′]copper(i) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983927/
https://www.ncbi.nlm.nih.gov/pubmed/21580482
http://dx.doi.org/10.1107/S1600536810007312
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AT ganxin triphenylphosphinekp111trisdiphenylphosphinomethylethanek3pppcopperitetrafluoridoborate

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