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(Triphenylphosphine-κP)[1,1,1-tris(diphenylphosphinomethyl)ethane-κ(3) P,P′,P′′]copper(I) tetrafluoridoborate

In the title mononuclear Cu(I) complex, [Cu(C(18)H(15)P)(C(41)H(39)P(3))]BF(4), the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetrahedral geometry, the distortion arising from the steric hindrance of...

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Detalles Bibliográficos
Autores principales:	Yin, Qi, Gan, Xin
Formato:	Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2010
Materias:	Metal-Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983927/ https://www.ncbi.nlm.nih.gov/pubmed/21580482 http://dx.doi.org/10.1107/S1600536810007312

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