Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene

The steric and electronic influence of backbone substitution in IMes-based (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) N-heterocyclic carbenes (NHC) was probed by synthesizing the [RhCl(CO)(2)(NHC)] series of complexes to quantify experimentally the Tolman electronic parameter (electro...

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Detalles Bibliográficos
Autores principales: Urbina-Blanco, César A, Bantreil, Xavier, Clavier, Hervé, Slawin, Alexandra M Z, Nolan, Steven P
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3002078/
https://www.ncbi.nlm.nih.gov/pubmed/21160916
http://dx.doi.org/10.3762/bjoc.6.128

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3002078/
https://www.ncbi.nlm.nih.gov/pubmed/21160916
http://dx.doi.org/10.3762/bjoc.6.128

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