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Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene

The steric and electronic influence of backbone substitution in IMes-based (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) N-heterocyclic carbenes (NHC) was probed by synthesizing the [RhCl(CO)(2)(NHC)] series of complexes to quantify experimentally the Tolman electronic parameter (electro...

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Detalles Bibliográficos
Autores principales:	Urbina-Blanco, César A, Bantreil, Xavier, Clavier, Hervé, Slawin, Alexandra M Z, Nolan, Steven P
Formato:	Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2010
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3002078/ https://www.ncbi.nlm.nih.gov/pubmed/21160916 http://dx.doi.org/10.3762/bjoc.6.128

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