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{Ba[Au(SCN)(2)](2)}(n): a three-dimensional net comprised of monomeric and trimeric gold(I) units

The noteworthy structural feature of the title complex, poly[acetonitrile­tetra-μ(2)-thio­cyanato-barium(II)digold(I)], {[Au(2)Ba(SCN)(4)(CH(3)CN)]}(n), is that the bis­(thio­cyanato)­aurate(I) anion adopts both monomeric and trimeric motifs. The trimer unit has an Au⋯Au distance of 3.1687 (3) Å. In...

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Detalles Bibliográficos
Autores principales: Back, A. Darren, Stroud, Tonia L., Schroll, Cynthia A., Coker, Nathan L., Krause, Jeanette A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007074/
https://www.ncbi.nlm.nih.gov/pubmed/21587698
http://dx.doi.org/10.1107/S1600536810021276