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Chloridobis{N-[(dimethylamino)dimethylsilyl]-2,6-dimethylanilido-κ(2) N,N′}titanium(III)
In the monomeric title titanium(III) compound, [Ti(C(12)H(21)N(2)Si)(2)Cl], the metal atom is surrounded by two N–silylated anilide ligands in an N,N′′-chelating mode. The two ends of the N—Si—N chelating unit exhibit different affinity to the metal center. The Ti—N(amine) bond is longer than the Ti...
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007402/ https://www.ncbi.nlm.nih.gov/pubmed/21588115 http://dx.doi.org/10.1107/S1600536810025092 |