Chloridobis{N-[(dimethyl­amino)­dimethyl­sil­yl]-2,6-dimethyl­anilido-κ(2) N,N′}titanium(III)

In the monomeric title titanium(III) compound, [Ti(C(12)H(21)N(2)Si)(2)Cl], the metal atom is surrounded by two N–silylated anilide ligands in an N,N′′-chelating mode. The two ends of the N—Si—N chelating unit exhibit different affinity to the metal center. The Ti—N(amine) bond is longer than the Ti...

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Autor principal: Chen, Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007402/
https://www.ncbi.nlm.nih.gov/pubmed/21588115
http://dx.doi.org/10.1107/S1600536810025092
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author Chen, Juan
author_facet Chen, Juan
author_sort Chen, Juan
collection PubMed
description In the monomeric title titanium(III) compound, [Ti(C(12)H(21)N(2)Si)(2)Cl], the metal atom is surrounded by two N–silylated anilide ligands in an N,N′′-chelating mode. The two ends of the N—Si—N chelating unit exhibit different affinity to the metal center. The Ti—N(amine) bond is longer than the Ti—N(anilide) bond by about 0.29 Å. The two ligands are arranged trans to each other and the mol­ecule demonstrates a pseudo-twofold rotation along the axis of the Ti—Cl bond. The five–coordinate Ti atom demonstrates a highly distorted trigonal-bipyramidal geometry.
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spelling pubmed-30074022010-12-30 Chloridobis{N-[(dimethyl­amino)­dimethyl­sil­yl]-2,6-dimethyl­anilido-κ(2) N,N′}titanium(III) Chen, Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric title titanium(III) compound, [Ti(C(12)H(21)N(2)Si)(2)Cl], the metal atom is surrounded by two N–silylated anilide ligands in an N,N′′-chelating mode. The two ends of the N—Si—N chelating unit exhibit different affinity to the metal center. The Ti—N(amine) bond is longer than the Ti—N(anilide) bond by about 0.29 Å. The two ligands are arranged trans to each other and the mol­ecule demonstrates a pseudo-twofold rotation along the axis of the Ti—Cl bond. The five–coordinate Ti atom demonstrates a highly distorted trigonal-bipyramidal geometry. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007402/ /pubmed/21588115 http://dx.doi.org/10.1107/S1600536810025092 Text en © Juan Chen 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Juan
Chloridobis{N-[(dimethyl­amino)­dimethyl­sil­yl]-2,6-dimethyl­anilido-κ(2) N,N′}titanium(III)
title Chloridobis{N-[(dimethyl­amino)­dimethyl­sil­yl]-2,6-dimethyl­anilido-κ(2) N,N′}titanium(III)
title_full Chloridobis{N-[(dimethyl­amino)­dimethyl­sil­yl]-2,6-dimethyl­anilido-κ(2) N,N′}titanium(III)
title_fullStr Chloridobis{N-[(dimethyl­amino)­dimethyl­sil­yl]-2,6-dimethyl­anilido-κ(2) N,N′}titanium(III)
title_full_unstemmed Chloridobis{N-[(dimethyl­amino)­dimethyl­sil­yl]-2,6-dimethyl­anilido-κ(2) N,N′}titanium(III)
title_short Chloridobis{N-[(dimethyl­amino)­dimethyl­sil­yl]-2,6-dimethyl­anilido-κ(2) N,N′}titanium(III)
title_sort chloridobis{n-[(dimethyl­amino)­dimethyl­sil­yl]-2,6-dimethyl­anilido-κ(2) n,n′}titanium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007402/
https://www.ncbi.nlm.nih.gov/pubmed/21588115
http://dx.doi.org/10.1107/S1600536810025092
work_keys_str_mv AT chenjuan chloridobisndimethylaminodimethylsilyl26dimethylanilidok2nntitaniumiii

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