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mer-Bis[2-(1,3-benzothiazol-2-yl)phenyl-κ(2) C (1),N][3-phenyl-5-(2-pyridyl)-1,2,4-triazol-1-ido-κ(2) N (1),N (5)]iridium(III) deuterochloro­form 3.5-solvate

In the title compound, [Ir(C(13)H(9)N(4))(C(13)H(8)NS)(2)]·3.5CDCl(3), the coordination at iridium is octa­hedral, but with narrow ligand bite angles. The bond lengths at iridium show the expected trans influence, with the Ir—N bonds trans to C being appreciably longer than those trans to N. The che...

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Detalles Bibliográficos
Autores principales: Jones, Peter G., Freund, Andreas, Weinkauf, Andreas, Kowalsky, Wolfgang, Johannes, Hans-Hermann
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007894/
https://www.ncbi.nlm.nih.gov/pubmed/21588505
http://dx.doi.org/10.1107/S1600536810031624