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(6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-κ(2) N (1),S]methyl}phenolato-κO (1))(triphenylphosphane-κP)nickel(II) chloride
The deprotonated Schiff base ligand in the title salt, [Ni(C(9)H(10)N(3)O(2)S)(C(18)H(15)P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated nickel(II) atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O—H⋯O hydrogen bond. The...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009342/ https://www.ncbi.nlm.nih.gov/pubmed/21588807 http://dx.doi.org/10.1107/S1600536810039292 |