(2S)-2-[(2S*,5R*,6R*)-5,6-Dimeth­oxy-5,6-dimethyl-1,4-dioxan-2-yl]-1-[(S)-1,1-dimethyl­ethylsulfon­yl]aziridine

The reaction of a sulfur ylide with a chiral non-racemic sulfinyl imine afforded the desired aziridine in excellent yield and subsequent oxidation of the sulfinyl moiety dissolved in anhydrous dichloro­methane using a 75% aqueous solution of 3-chloro­per­oxy­benzoic acid afforded the title compound,...

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Detalles Bibliográficos
Autores principales: Moragas Solà, Toni, Lewis, William, Bettigeri, Sampada V., Stockman, Robert A., Forbes, David C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011582/
https://www.ncbi.nlm.nih.gov/pubmed/21589609
http://dx.doi.org/10.1107/S1600536810048816

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011582/
https://www.ncbi.nlm.nih.gov/pubmed/21589609
http://dx.doi.org/10.1107/S1600536810048816

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