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Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate

The title compound, C(36)H(30)NP(2) (+)·Br(−)·C(2)H(3)N, crystallized from a CH(3)CN/OEt(2) solution as an acetonitrile solvate. The central P—N—P angle [142.88 (10)°] is significantly larger than in the corresponding chloride and iodide structures.

Detalles Bibliográficos
Autores principales: Knapp, Carsten, Uzun, Rabiya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011659/
https://www.ncbi.nlm.nih.gov/pubmed/21589481
http://dx.doi.org/10.1107/S1600536810046337