Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate

The title compound, C(36)H(30)NP(2) (+)·Br(−)·C(2)H(3)N, crystallized from a CH(3)CN/OEt(2) solution as an acetonitrile solvate. The central P—N—P angle [142.88 (10)°] is significantly larger than in the corresponding chloride and iodide structures.

Detalles Bibliográficos
Autores principales: Knapp, Carsten, Uzun, Rabiya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011659/
https://www.ncbi.nlm.nih.gov/pubmed/21589481
http://dx.doi.org/10.1107/S1600536810046337
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author Knapp, Carsten
Uzun, Rabiya
author_facet Knapp, Carsten
Uzun, Rabiya
author_sort Knapp, Carsten
collection PubMed
description The title compound, C(36)H(30)NP(2) (+)·Br(−)·C(2)H(3)N, crystallized from a CH(3)CN/OEt(2) solution as an acetonitrile solvate. The central P—N—P angle [142.88 (10)°] is significantly larger than in the corresponding chloride and iodide structures.
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spelling pubmed-30116592010-12-30 Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate Knapp, Carsten Uzun, Rabiya Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(36)H(30)NP(2) (+)·Br(−)·C(2)H(3)N, crystallized from a CH(3)CN/OEt(2) solution as an acetonitrile solvate. The central P—N—P angle [142.88 (10)°] is significantly larger than in the corresponding chloride and iodide structures. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011659/ /pubmed/21589481 http://dx.doi.org/10.1107/S1600536810046337 Text en © Knapp and Uzun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Knapp, Carsten
Uzun, Rabiya
Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate
title Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate
title_full Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate
title_fullStr Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate
title_full_unstemmed Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate
title_short Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate
title_sort bis(triphenylphosphine)iminium bromide acetonitrile monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011659/
https://www.ncbi.nlm.nih.gov/pubmed/21589481
http://dx.doi.org/10.1107/S1600536810046337
work_keys_str_mv AT knappcarsten bistriphenylphosphineiminiumbromideacetonitrilemonosolvate
AT uzunrabiya bistriphenylphosphineiminiumbromideacetonitrilemonosolvate

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