Cobalt 1,3-Diisopropyl-1H-imidazol-2-ylidene Complexes: Synthesis, Solid-State Structures, and Quantum Chemistry Calculations

[Image: see text] The reaction of (η(5)-C(5)H(5))Co(PPh(3))(2) (1) with 1,3-bis(isopropyl)imidazol-2-ylidene (Im(i)Pr(2), 17) leads to the formation of (η(5)-C(5)H(5))Co(PPh(3))(Im(i)Pr(2)) (5) in 69% yield. N-Heterocyclic carbene 17 also undergoes reaction with (η(5)-C(5)H(5))Co(CO)(2) (9) to give...

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Detalles Bibliográficos
Autores principales: Vélez, Carmen L., Markwick, Phineus R. L., Holland, Ryan L., DiPasquale, Antonio G., Rheingold, Arnold L., O’Connor, Joseph M.
Formato: Texto
Lenguaje:English
Publicado: American Chemical Society 2010
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3014667/
https://www.ncbi.nlm.nih.gov/pubmed/21212838
http://dx.doi.org/10.1021/om100680c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3014667/
https://www.ncbi.nlm.nih.gov/pubmed/21212838
http://dx.doi.org/10.1021/om100680c

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