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cis-Di-μ-oxido-bis[(N,N-diethyldithiocarbamato-κ(2) S,S′)oxidomolybdenum(V)](Mo—Mo) tetrahydrofuran monosolvate
The title compound, [Mo(2)(C(5)H(10)NS(2))(2)O(4)]·C(4)H(8)O, can be readily prepared in tetrahydrofuran (THF) by an oxidation reaction between the Mo(IV) precursor [MoO(S(2)CNEt(2))(2)] with [ReMeO(3)]. The compound is an axially symmetric Mo(V) dimer (2 symmetry), in which the metal atoms exhibi...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051765/ https://www.ncbi.nlm.nih.gov/pubmed/21522931 http://dx.doi.org/10.1107/S1600536811003187 |