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Formation of macrocyclic lactones in the Paternò–Büchi dimerization reaction

Furan-2-ylmethyl 2-oxoacetates 1a,b, in which the furan ring and the carbonyl moiety were embedded intramolecularly, were synthesized from commercially available furan-2-ylmethanol and their photochemical reaction (hν > 290 nm) was investigated. Twelve-membered macrocyclic lactones 2a,b with C(i)...

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Detalles Bibliográficos
Autores principales: Arimura, Junya, Mizuta, Tsutomu, Hiraga, Yoshikazu, Abe, Manabu
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3063007/
https://www.ncbi.nlm.nih.gov/pubmed/21448243
http://dx.doi.org/10.3762/bjoc.7.35