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Application of the diastereoselective photodeconjugation of α,β-unsaturated esters to the synthesis of gymnastatin H
The asymmetric synthesis of gymnastatin H has been achieved by using the photoisomerisation of a conjugated ester to its β,γ-unsaturated isomer through the protonation of a in situ generated dienol as key step. Thanks to diacetone D-glucose used as a chiral alkoxy group, the protonation occurred wel...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3064449/ https://www.ncbi.nlm.nih.gov/pubmed/21448437 http://dx.doi.org/10.3762/bjoc.7.21 |