Cargando…
On the Stereochemistry of 2-Hydroxyethylphosphonate Dioxygenase
[Image: see text] Stereochemical investigations have shown that the conversion of 2-hydroxyethylphosphonate to hydroxymethylphosphonate by the enzyme HEPD involves removal of the pro-S hydrogen at C2 and, surprisingly, the loss of stereochemical information at C1. As a result, the mechanisms previou...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2011
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3069692/ https://www.ncbi.nlm.nih.gov/pubmed/21381767 http://dx.doi.org/10.1021/ja1113326 |