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{2-[(η(5)-Cyclopentadienyl)diphenylmethyl]-1H-imidazolido-κN}bis(N,N-diethylamido)titanium(IV)
The chemically achiral title molecule, [Ti(C(4)H(10)N)(2)(C(21)H(16)N(2))], crystallizes in the chiral space group P2(1). All three N atoms coordinating to the Ti(IV) atom adopt planar environments [sums of valence angles = 359.5 (6), 360.0 (7) and 360.0 (6)°], which is indicative of pπ–dπ donation...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089115/ https://www.ncbi.nlm.nih.gov/pubmed/21754286 http://dx.doi.org/10.1107/S1600536811012396 |