{2-[(η(5)-Cyclo­penta­dien­yl)diphenyl­meth­yl]-1H-imidazolido-κN}bis­(N,N-diethyl­amido)­titanium(IV)

The chemically achiral title mol­ecule, [Ti(C(4)H(10)N)(2)(C(21)H(16)N(2))], crystallizes in the chiral space group P2(1). All three N atoms coordinating to the Ti(IV) atom adopt planar environments [sums of valence angles = 359.5 (6), 360.0 (7) and 360.0 (6)°], which is indicative of pπ–dπ donation...

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Detalles Bibliográficos
Autores principales: Cai, Xianfeng, Xu, Yingying, Nie, Wanli, Borzov, Maxim V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089115/
https://www.ncbi.nlm.nih.gov/pubmed/21754286
http://dx.doi.org/10.1107/S1600536811012396
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author Cai, Xianfeng
Xu, Yingying
Nie, Wanli
Borzov, Maxim V.
author_facet Cai, Xianfeng
Xu, Yingying
Nie, Wanli
Borzov, Maxim V.
author_sort Cai, Xianfeng
collection PubMed
description The chemically achiral title mol­ecule, [Ti(C(4)H(10)N)(2)(C(21)H(16)N(2))], crystallizes in the chiral space group P2(1). All three N atoms coordinating to the Ti(IV) atom adopt planar environments [sums of valence angles = 359.5 (6), 360.0 (7) and 360.0 (6)°], which is indicative of pπ–dπ donation from all of these N atoms to the metal and, thus, of the formal 18 e(−) nature of the complex. The overall coordination about the Ti(IV) atom is distorted tetra­hedral, assuming the cyclo­penta­dienyl ring occupies one coordination site. The Ti—N(imidazole) amide-type bond is longer by approximately 0.16 Å than the other two Ti—N(amide) bonds.
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spelling pubmed-30891152011-07-13 {2-[(η(5)-Cyclo­penta­dien­yl)diphenyl­meth­yl]-1H-imidazolido-κN}bis­(N,N-diethyl­amido)­titanium(IV) Cai, Xianfeng Xu, Yingying Nie, Wanli Borzov, Maxim V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The chemically achiral title mol­ecule, [Ti(C(4)H(10)N)(2)(C(21)H(16)N(2))], crystallizes in the chiral space group P2(1). All three N atoms coordinating to the Ti(IV) atom adopt planar environments [sums of valence angles = 359.5 (6), 360.0 (7) and 360.0 (6)°], which is indicative of pπ–dπ donation from all of these N atoms to the metal and, thus, of the formal 18 e(−) nature of the complex. The overall coordination about the Ti(IV) atom is distorted tetra­hedral, assuming the cyclo­penta­dienyl ring occupies one coordination site. The Ti—N(imidazole) amide-type bond is longer by approximately 0.16 Å than the other two Ti—N(amide) bonds. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089115/ /pubmed/21754286 http://dx.doi.org/10.1107/S1600536811012396 Text en © Cai et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Xianfeng
Xu, Yingying
Nie, Wanli
Borzov, Maxim V.
{2-[(η(5)-Cyclo­penta­dien­yl)diphenyl­meth­yl]-1H-imidazolido-κN}bis­(N,N-diethyl­amido)­titanium(IV)
title {2-[(η(5)-Cyclo­penta­dien­yl)diphenyl­meth­yl]-1H-imidazolido-κN}bis­(N,N-diethyl­amido)­titanium(IV)
title_full {2-[(η(5)-Cyclo­penta­dien­yl)diphenyl­meth­yl]-1H-imidazolido-κN}bis­(N,N-diethyl­amido)­titanium(IV)
title_fullStr {2-[(η(5)-Cyclo­penta­dien­yl)diphenyl­meth­yl]-1H-imidazolido-κN}bis­(N,N-diethyl­amido)­titanium(IV)
title_full_unstemmed {2-[(η(5)-Cyclo­penta­dien­yl)diphenyl­meth­yl]-1H-imidazolido-κN}bis­(N,N-diethyl­amido)­titanium(IV)
title_short {2-[(η(5)-Cyclo­penta­dien­yl)diphenyl­meth­yl]-1H-imidazolido-κN}bis­(N,N-diethyl­amido)­titanium(IV)
title_sort {2-[(η(5)-cyclo­penta­dien­yl)diphenyl­meth­yl]-1h-imidazolido-κn}bis­(n,n-diethyl­amido)­titanium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089115/
https://www.ncbi.nlm.nih.gov/pubmed/21754286
http://dx.doi.org/10.1107/S1600536811012396
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AT xuyingying 2ē5cyclopentadienyldiphenylmethyl1himidazolidoknbisnndiethylamidotitaniumiv
AT niewanli 2ē5cyclopentadienyldiphenylmethyl1himidazolidoknbisnndiethylamidotitaniumiv
AT borzovmaximv 2ē5cyclopentadienyldiphenylmethyl1himidazolidoknbisnndiethylamidotitaniumiv

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