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Bis[2-methoxy-6-(phenyliminiomethyl)phenolate-κ(2) O,O′]bis(thiocyanato-κN)manganese(II)
The Mn(II) atom in the title complex, [Mn(NCS)(2)(C(14)H(13)NO(2))(2)], lies on a center of inversion in a MnO(4)N(2) octahedral geometry. The Schiff base is present in its zwitterionic form and is O,O′-chelated to the metal atom. The imino N atom is protonated and is involved in an intramolecular...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099895/ https://www.ncbi.nlm.nih.gov/pubmed/21753979 http://dx.doi.org/10.1107/S1600536811009330 |