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Bis[2-methoxy-6-(phenyliminiomethyl)phenolate-κ(2) O,O′]bis(thiocyanato-κN)manganese(II)
The Mn(II) atom in the title complex, [Mn(NCS)(2)(C(14)H(13)NO(2))(2)], lies on a center of inversion in a MnO(4)N(2) octahedral geometry. The Schiff base is present in its zwitterionic form and is O,O′-chelated to the metal atom. The imino N atom is protonated and is involved in an intramolecular...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099895/ https://www.ncbi.nlm.nih.gov/pubmed/21753979 http://dx.doi.org/10.1107/S1600536811009330 |
| _version_ | 1782204110310735872 |
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| author | Shen, Jin-Bei Ge, Guo-Di Zhao, Guo-Liang |
| author_facet | Shen, Jin-Bei Ge, Guo-Di Zhao, Guo-Liang |
| author_sort | Shen, Jin-Bei |
| collection | PubMed |
| description | The Mn(II) atom in the title complex, [Mn(NCS)(2)(C(14)H(13)NO(2))(2)], lies on a center of inversion in a MnO(4)N(2) octahedral geometry. The Schiff base is present in its zwitterionic form and is O,O′-chelated to the metal atom. The imino N atom is protonated and is involved in an intramolecular hydrogen bond with the phenolate O atom. |
| format | Text |
| id | pubmed-3099895 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30998952011-07-13 Bis[2-methoxy-6-(phenyliminiomethyl)phenolate-κ(2) O,O′]bis(thiocyanato-κN)manganese(II) Shen, Jin-Bei Ge, Guo-Di Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(II) atom in the title complex, [Mn(NCS)(2)(C(14)H(13)NO(2))(2)], lies on a center of inversion in a MnO(4)N(2) octahedral geometry. The Schiff base is present in its zwitterionic form and is O,O′-chelated to the metal atom. The imino N atom is protonated and is involved in an intramolecular hydrogen bond with the phenolate O atom. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3099895/ /pubmed/21753979 http://dx.doi.org/10.1107/S1600536811009330 Text en © Shen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shen, Jin-Bei Ge, Guo-Di Zhao, Guo-Liang Bis[2-methoxy-6-(phenyliminiomethyl)phenolate-κ(2) O,O′]bis(thiocyanato-κN)manganese(II) |
| title | Bis[2-methoxy-6-(phenyliminiomethyl)phenolate-κ(2)
O,O′]bis(thiocyanato-κN)manganese(II) |
| title_full | Bis[2-methoxy-6-(phenyliminiomethyl)phenolate-κ(2)
O,O′]bis(thiocyanato-κN)manganese(II) |
| title_fullStr | Bis[2-methoxy-6-(phenyliminiomethyl)phenolate-κ(2)
O,O′]bis(thiocyanato-κN)manganese(II) |
| title_full_unstemmed | Bis[2-methoxy-6-(phenyliminiomethyl)phenolate-κ(2)
O,O′]bis(thiocyanato-κN)manganese(II) |
| title_short | Bis[2-methoxy-6-(phenyliminiomethyl)phenolate-κ(2)
O,O′]bis(thiocyanato-κN)manganese(II) |
| title_sort | bis[2-methoxy-6-(phenyliminiomethyl)phenolate-κ(2)
o,o′]bis(thiocyanato-κn)manganese(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099895/ https://www.ncbi.nlm.nih.gov/pubmed/21753979 http://dx.doi.org/10.1107/S1600536811009330 |
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