Cell-free H-cluster Synthesis and [FeFe] Hydrogenase Activation: All Five CO and CN(−) Ligands Derive from Tyrosine

[FeFe] hydrogenases are promising catalysts for producing hydrogen as a sustainable fuel and chemical feedstock, and they also serve as paradigms for biomimetic hydrogen-evolving compounds. Hydrogen formation is catalyzed by the H-cluster, a unique iron-based cofactor requiring three carbon monoxide...

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Detalles Bibliográficos
Autores principales: Kuchenreuther, Jon M., George, Simon J., Grady-Smith, Celestine S., Cramer, Stephen P., Swartz, James R.
Formato: Texto
Lenguaje:English
Publicado: Public Library of Science 2011
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3105041/
https://www.ncbi.nlm.nih.gov/pubmed/21673792
http://dx.doi.org/10.1371/journal.pone.0020346

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3105041/
https://www.ncbi.nlm.nih.gov/pubmed/21673792
http://dx.doi.org/10.1371/journal.pone.0020346

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