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Cell-free H-cluster Synthesis and [FeFe] Hydrogenase Activation: All Five CO and CN(−) Ligands Derive from Tyrosine
[FeFe] hydrogenases are promising catalysts for producing hydrogen as a sustainable fuel and chemical feedstock, and they also serve as paradigms for biomimetic hydrogen-evolving compounds. Hydrogen formation is catalyzed by the H-cluster, a unique iron-based cofactor requiring three carbon monoxide...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Public Library of Science
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3105041/ https://www.ncbi.nlm.nih.gov/pubmed/21673792 http://dx.doi.org/10.1371/journal.pone.0020346 |