Gold-catalyzed naphthalene functionalization

The complexes IPrMCl (IPr = 1,3-bis(diisopropylphenyl)imidazol-2-ylidene, M = Cu, 1a; M = Au, 1b), in the presence of one equiv of NaBAr'(4) (Ar' = 3,5-bis(trifluoromethyl)phenyl), catalyze the transfer of carbene groups: C(R)CO(2)Et (R = H, Me) from N(2)C(R)CO(2)Et to afford products that...

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Detalles Bibliográficos
Autores principales: Pérez, Pedro J, Díaz-Requejo, M Mar, Rivilla, Iván
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3107446/
https://www.ncbi.nlm.nih.gov/pubmed/21647320
http://dx.doi.org/10.3762/bjoc.7.77

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3107446/
https://www.ncbi.nlm.nih.gov/pubmed/21647320
http://dx.doi.org/10.3762/bjoc.7.77

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