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Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes

A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.

Detalles Bibliográficos
Autores principales: Miura, Tomoya, Biyajima, Tsuneaki, Toyoshima, Takeharu, Murakami, Masahiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3107559/
https://www.ncbi.nlm.nih.gov/pubmed/21647266
http://dx.doi.org/10.3762/bjoc.7.67