Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes

A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.

Detalles Bibliográficos
Autores principales: Miura, Tomoya, Biyajima, Tsuneaki, Toyoshima, Takeharu, Murakami, Masahiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3107559/
https://www.ncbi.nlm.nih.gov/pubmed/21647266
http://dx.doi.org/10.3762/bjoc.7.67
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author Miura, Tomoya
Biyajima, Tsuneaki
Toyoshima, Takeharu
Murakami, Masahiro
author_facet Miura, Tomoya
Biyajima, Tsuneaki
Toyoshima, Takeharu
Murakami, Masahiro
author_sort Miura, Tomoya
collection PubMed
description A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.
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spelling pubmed-31075592011-06-06 Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes Miura, Tomoya Biyajima, Tsuneaki Toyoshima, Takeharu Murakami, Masahiro Beilstein J Org Chem Full Research Paper A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst. Beilstein-Institut 2011-05-09 /pmc/articles/PMC3107559/ /pubmed/21647266 http://dx.doi.org/10.3762/bjoc.7.67 Text en Copyright © 2011, Miura et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Miura, Tomoya
Biyajima, Tsuneaki
Toyoshima, Takeharu
Murakami, Masahiro
Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes
title Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes
title_full Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes
title_fullStr Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes
title_full_unstemmed Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes
title_short Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes
title_sort synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3107559/
https://www.ncbi.nlm.nih.gov/pubmed/21647266
http://dx.doi.org/10.3762/bjoc.7.67
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AT toyoshimatakeharu synthesisofcrossconjugatedtrienesbyrhodiumcatalyzeddimerizationofmonosubstitutedallenes
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