Highly Unsaturated Binuclear Butadiene Iron Carbonyls: Quintet Spin States, Perpendicular Structures, Agostic Hydrogen Atoms, and Iron-Iron Multiple Bonds

The highly unsaturated binuclear butadiene iron carbonyls (C(4)H(6))(2)Fe(2)(CO)(n) (n = 2, 1) have been examined using density functional theory. For (C(4)H(6))(2)Fe(2)(CO)(n) (n = 2, 1), both coaxial and perpendicular structures are found. The global minima of (C(4)H(6))(2)Fe(2)(CO)(n) (n = 2, 1)...

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Detalles Bibliográficos
Autores principales: Zeng, Yi, Wang, Shijian, Feng, Hao, Xie, Yaoming, King, R. Bruce
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2011
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3127113/
https://www.ncbi.nlm.nih.gov/pubmed/21731437
http://dx.doi.org/10.3390/ijms12042216

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3127113/
https://www.ncbi.nlm.nih.gov/pubmed/21731437
http://dx.doi.org/10.3390/ijms12042216

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