Cargando…

Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers

A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold(I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions.

Detalles Bibliográficos
Autores principales: Istrate, Florin M, Gagosz, Fabien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135071/
https://www.ncbi.nlm.nih.gov/pubmed/21804884
http://dx.doi.org/10.3762/bjoc.7.100