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Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers
A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold(I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions.
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135071/ https://www.ncbi.nlm.nih.gov/pubmed/21804884 http://dx.doi.org/10.3762/bjoc.7.100 |
| _version_ | 1782208052984807424 |
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| author | Istrate, Florin M Gagosz, Fabien |
| author_facet | Istrate, Florin M Gagosz, Fabien |
| author_sort | Istrate, Florin M |
| collection | PubMed |
| description | A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold(I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions. |
| format | Online Article Text |
| id | pubmed-3135071 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31350712011-07-29 Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers Istrate, Florin M Gagosz, Fabien Beilstein J Org Chem Letter A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold(I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions. Beilstein-Institut 2011-06-29 /pmc/articles/PMC3135071/ /pubmed/21804884 http://dx.doi.org/10.3762/bjoc.7.100 Text en Copyright © 2011, Istrate and Gagosz https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Letter Istrate, Florin M Gagosz, Fabien Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers |
| title | Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers |
| title_full | Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers |
| title_fullStr | Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers |
| title_full_unstemmed | Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers |
| title_short | Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers |
| title_sort | gold(i)-catalyzed formation of furans by a claisen-type rearrangement of ynenyl allyl ethers |
| topic | Letter |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135071/ https://www.ncbi.nlm.nih.gov/pubmed/21804884 http://dx.doi.org/10.3762/bjoc.7.100 |
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