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Gold-catalyzed propargylic substitutions: Scope and synthetic developments

This personal account summarizes our recent developments in gold-catalyzed direct substitutions on propargylic (allylic, benzylic) alcohols, with various nucleophiles (and bi-nucleophiles) based on the σ- and/or π-acidity of gold(III) complexes. Synthetic developments are also briefly described.

Detalles Bibliográficos
Autores principales: Debleds, Olivier, Gayon, Eric, Vrancken, Emmanuel, Campagne, Jean-Marc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135077/
https://www.ncbi.nlm.nih.gov/pubmed/21804883
http://dx.doi.org/10.3762/bjoc.7.99