Cargando…
Gold-catalyzed propargylic substitutions: Scope and synthetic developments
This personal account summarizes our recent developments in gold-catalyzed direct substitutions on propargylic (allylic, benzylic) alcohols, with various nucleophiles (and bi-nucleophiles) based on the σ- and/or π-acidity of gold(III) complexes. Synthetic developments are also briefly described.
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135077/ https://www.ncbi.nlm.nih.gov/pubmed/21804883 http://dx.doi.org/10.3762/bjoc.7.99 |
| _version_ | 1782208054308110336 |
|---|---|
| author | Debleds, Olivier Gayon, Eric Vrancken, Emmanuel Campagne, Jean-Marc |
| author_facet | Debleds, Olivier Gayon, Eric Vrancken, Emmanuel Campagne, Jean-Marc |
| author_sort | Debleds, Olivier |
| collection | PubMed |
| description | This personal account summarizes our recent developments in gold-catalyzed direct substitutions on propargylic (allylic, benzylic) alcohols, with various nucleophiles (and bi-nucleophiles) based on the σ- and/or π-acidity of gold(III) complexes. Synthetic developments are also briefly described. |
| format | Online Article Text |
| id | pubmed-3135077 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31350772011-07-29 Gold-catalyzed propargylic substitutions: Scope and synthetic developments Debleds, Olivier Gayon, Eric Vrancken, Emmanuel Campagne, Jean-Marc Beilstein J Org Chem Review This personal account summarizes our recent developments in gold-catalyzed direct substitutions on propargylic (allylic, benzylic) alcohols, with various nucleophiles (and bi-nucleophiles) based on the σ- and/or π-acidity of gold(III) complexes. Synthetic developments are also briefly described. Beilstein-Institut 2011-06-28 /pmc/articles/PMC3135077/ /pubmed/21804883 http://dx.doi.org/10.3762/bjoc.7.99 Text en Copyright © 2011, Debleds et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Review Debleds, Olivier Gayon, Eric Vrancken, Emmanuel Campagne, Jean-Marc Gold-catalyzed propargylic substitutions: Scope and synthetic developments |
| title | Gold-catalyzed propargylic substitutions: Scope and synthetic developments |
| title_full | Gold-catalyzed propargylic substitutions: Scope and synthetic developments |
| title_fullStr | Gold-catalyzed propargylic substitutions: Scope and synthetic developments |
| title_full_unstemmed | Gold-catalyzed propargylic substitutions: Scope and synthetic developments |
| title_short | Gold-catalyzed propargylic substitutions: Scope and synthetic developments |
| title_sort | gold-catalyzed propargylic substitutions: scope and synthetic developments |
| topic | Review |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135077/ https://www.ncbi.nlm.nih.gov/pubmed/21804883 http://dx.doi.org/10.3762/bjoc.7.99 |
| work_keys_str_mv | AT debledsolivier goldcatalyzedpropargylicsubstitutionsscopeandsyntheticdevelopments AT gayoneric goldcatalyzedpropargylicsubstitutionsscopeandsyntheticdevelopments AT vranckenemmanuel goldcatalyzedpropargylicsubstitutionsscopeandsyntheticdevelopments AT campagnejeanmarc goldcatalyzedpropargylicsubstitutionsscopeandsyntheticdevelopments |