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The role of silver additives in gold-mediated C–H functionalisation

The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C–H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given.

Detalles Bibliográficos
Autores principales: Patrick, Scott R, Boogaerts, Ine I F, Gaillard, Sylvain, Slawin, Alexandra M Z, Nolan, Steven P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135131/
https://www.ncbi.nlm.nih.gov/pubmed/21804886
http://dx.doi.org/10.3762/bjoc.7.102