The role of silver additives in gold-mediated C–H functionalisation

The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C–H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given.

Detalles Bibliográficos
Autores principales: Patrick, Scott R, Boogaerts, Ine I F, Gaillard, Sylvain, Slawin, Alexandra M Z, Nolan, Steven P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135131/
https://www.ncbi.nlm.nih.gov/pubmed/21804886
http://dx.doi.org/10.3762/bjoc.7.102
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author Patrick, Scott R
Boogaerts, Ine I F
Gaillard, Sylvain
Slawin, Alexandra M Z
Nolan, Steven P
author_facet Patrick, Scott R
Boogaerts, Ine I F
Gaillard, Sylvain
Slawin, Alexandra M Z
Nolan, Steven P
author_sort Patrick, Scott R
collection PubMed
description The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C–H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given.
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spelling pubmed-31351312011-07-29 The role of silver additives in gold-mediated C–H functionalisation Patrick, Scott R Boogaerts, Ine I F Gaillard, Sylvain Slawin, Alexandra M Z Nolan, Steven P Beilstein J Org Chem Full Research Paper The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C–H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given. Beilstein-Institut 2011-07-01 /pmc/articles/PMC3135131/ /pubmed/21804886 http://dx.doi.org/10.3762/bjoc.7.102 Text en Copyright © 2011, Patrick et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Patrick, Scott R
Boogaerts, Ine I F
Gaillard, Sylvain
Slawin, Alexandra M Z
Nolan, Steven P
The role of silver additives in gold-mediated C–H functionalisation
title The role of silver additives in gold-mediated C–H functionalisation
title_full The role of silver additives in gold-mediated C–H functionalisation
title_fullStr The role of silver additives in gold-mediated C–H functionalisation
title_full_unstemmed The role of silver additives in gold-mediated C–H functionalisation
title_short The role of silver additives in gold-mediated C–H functionalisation
title_sort role of silver additives in gold-mediated c–h functionalisation
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135131/
https://www.ncbi.nlm.nih.gov/pubmed/21804886
http://dx.doi.org/10.3762/bjoc.7.102
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