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A comparative study of the Au-catalyzed cyclization of hydroxy-substituted allylic alcohols and ethers

The Au(I)-catalyzed cyclization of hydroxyallylic ethers to form tetrahydropyrans is reported. Employing (acetonitrile)[(o-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate, the cyclization reactions were complete within minutes to hours, depending on the substrate. The reaction progress...

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Detalles Bibliográficos
Autores principales: Biannic, Berenger, Ghebreghiorgis, Thomas, Aponick, Aaron
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135158/
https://www.ncbi.nlm.nih.gov/pubmed/21804875
http://dx.doi.org/10.3762/bjoc.7.91