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Highly efficient gold(I)-catalyzed Overman rearrangement in water

A highly efficient gold(I)-catalyzed Overman rearrangement of allylic trichloroacetimidates to allylic trichloroacetamides in water is reported. With this environmentally benign and scalable protocol, a series of C3-alkyl substituted allylic trichloroacetamides were synthesized in good to high yield...

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Detalles Bibliográficos
Autores principales: Xing, Dong, Yang, Dan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135174/
https://www.ncbi.nlm.nih.gov/pubmed/21804872
http://dx.doi.org/10.3762/bjoc.7.88