Highly efficient gold(I)-catalyzed Overman rearrangement in water

A highly efficient gold(I)-catalyzed Overman rearrangement of allylic trichloroacetimidates to allylic trichloroacetamides in water is reported. With this environmentally benign and scalable protocol, a series of C3-alkyl substituted allylic trichloroacetamides were synthesized in good to high yield...

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Detalles Bibliográficos
Autores principales: Xing, Dong, Yang, Dan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135174/
https://www.ncbi.nlm.nih.gov/pubmed/21804872
http://dx.doi.org/10.3762/bjoc.7.88
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author Xing, Dong
Yang, Dan
author_facet Xing, Dong
Yang, Dan
author_sort Xing, Dong
collection PubMed
description A highly efficient gold(I)-catalyzed Overman rearrangement of allylic trichloroacetimidates to allylic trichloroacetamides in water is reported. With this environmentally benign and scalable protocol, a series of C3-alkyl substituted allylic trichloroacetamides were synthesized in good to high yields.
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spelling pubmed-31351742011-07-29 Highly efficient gold(I)-catalyzed Overman rearrangement in water Xing, Dong Yang, Dan Beilstein J Org Chem Letter A highly efficient gold(I)-catalyzed Overman rearrangement of allylic trichloroacetimidates to allylic trichloroacetamides in water is reported. With this environmentally benign and scalable protocol, a series of C3-alkyl substituted allylic trichloroacetamides were synthesized in good to high yields. Beilstein-Institut 2011-06-08 /pmc/articles/PMC3135174/ /pubmed/21804872 http://dx.doi.org/10.3762/bjoc.7.88 Text en Copyright © 2011, Xing and Yang https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Xing, Dong
Yang, Dan
Highly efficient gold(I)-catalyzed Overman rearrangement in water
title Highly efficient gold(I)-catalyzed Overman rearrangement in water
title_full Highly efficient gold(I)-catalyzed Overman rearrangement in water
title_fullStr Highly efficient gold(I)-catalyzed Overman rearrangement in water
title_full_unstemmed Highly efficient gold(I)-catalyzed Overman rearrangement in water
title_short Highly efficient gold(I)-catalyzed Overman rearrangement in water
title_sort highly efficient gold(i)-catalyzed overman rearrangement in water
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135174/
https://www.ncbi.nlm.nih.gov/pubmed/21804872
http://dx.doi.org/10.3762/bjoc.7.88
work_keys_str_mv AT xingdong highlyefficientgoldicatalyzedovermanrearrangementinwater
AT yangdan highlyefficientgoldicatalyzedovermanrearrangementinwater

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