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Di-μ-oxido-bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)dimangan­ese(III,IV)] bis­(tetra­phenyl­borate) chloride acetonitrile disolvate

The title compound, [Mn(2)O(2)(C(10)H(24)N(4))(2)](C(24)H(20)B)(2)Cl·2CH(3)CN, is a mixed-valent Mn(III)/Mn(IV) oxide-bridged mangan­ese dimer with one chloride and two tetra­phenyl­borate counter-anions. There are two non-coordinated mol­ecules of acetonitrile in the formula unit. A center of inver...

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Detalles Bibliográficos
Autores principales: Olmstead, Marilyn M., Boyce, David W., Bria, Lauren E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151985/
https://www.ncbi.nlm.nih.gov/pubmed/21836836
http://dx.doi.org/10.1107/S1600536811019829