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Di-μ-oxido-bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)dimangan­ese(III,IV)] bis­(tetra­phenyl­borate) chloride acetonitrile disolvate

The title compound, [Mn(2)O(2)(C(10)H(24)N(4))(2)](C(24)H(20)B)(2)Cl·2CH(3)CN, is a mixed-valent Mn(III)/Mn(IV) oxide-bridged mangan­ese dimer with one chloride and two tetra­phenyl­borate counter-anions. There are two non-coordinated mol­ecules of acetonitrile in the formula unit. A center of inver...

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Autores principales: Olmstead, Marilyn M., Boyce, David W., Bria, Lauren E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151985/
https://www.ncbi.nlm.nih.gov/pubmed/21836836
http://dx.doi.org/10.1107/S1600536811019829
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author Olmstead, Marilyn M.
Boyce, David W.
Bria, Lauren E.
author_facet Olmstead, Marilyn M.
Boyce, David W.
Bria, Lauren E.
author_sort Olmstead, Marilyn M.
collection PubMed
description The title compound, [Mn(2)O(2)(C(10)H(24)N(4))(2)](C(24)H(20)B)(2)Cl·2CH(3)CN, is a mixed-valent Mn(III)/Mn(IV) oxide-bridged mangan­ese dimer with one chloride and two tetra­phenyl­borate counter-anions. There are two non-coordinated mol­ecules of acetonitrile in the formula unit. A center of inversion is present between the two metal atoms, and, consequently, there is no distinction between Mn(III) and Mn(IV) metal centers. In the Mn(2)O(2) core, the Mn—O distances are 1.817 (3) and 1.821 (3) Å. The cyclam ligand is in the cis configuration. The chloride counter-anion resides on a center of symmetry, whereas the tetra­phenyl­borate counter-anion is in a general position. The cyclam ligand is hydrogen bonded to the acetonitrile as well as to the chloride anion. One of the phenyl rings of the anion and the acetonitrile solvent molecule are each disordered over two sets of sites.
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spelling pubmed-31519852011-08-11 Di-μ-oxido-bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)dimangan­ese(III,IV)] bis­(tetra­phenyl­borate) chloride acetonitrile disolvate Olmstead, Marilyn M. Boyce, David W. Bria, Lauren E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(2)O(2)(C(10)H(24)N(4))(2)](C(24)H(20)B)(2)Cl·2CH(3)CN, is a mixed-valent Mn(III)/Mn(IV) oxide-bridged mangan­ese dimer with one chloride and two tetra­phenyl­borate counter-anions. There are two non-coordinated mol­ecules of acetonitrile in the formula unit. A center of inversion is present between the two metal atoms, and, consequently, there is no distinction between Mn(III) and Mn(IV) metal centers. In the Mn(2)O(2) core, the Mn—O distances are 1.817 (3) and 1.821 (3) Å. The cyclam ligand is in the cis configuration. The chloride counter-anion resides on a center of symmetry, whereas the tetra­phenyl­borate counter-anion is in a general position. The cyclam ligand is hydrogen bonded to the acetonitrile as well as to the chloride anion. One of the phenyl rings of the anion and the acetonitrile solvent molecule are each disordered over two sets of sites. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151985/ /pubmed/21836836 http://dx.doi.org/10.1107/S1600536811019829 Text en © Olmstead et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Olmstead, Marilyn M.
Boyce, David W.
Bria, Lauren E.
Di-μ-oxido-bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)dimangan­ese(III,IV)] bis­(tetra­phenyl­borate) chloride acetonitrile disolvate
title Di-μ-oxido-bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)dimangan­ese(III,IV)] bis­(tetra­phenyl­borate) chloride acetonitrile disolvate
title_full Di-μ-oxido-bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)dimangan­ese(III,IV)] bis­(tetra­phenyl­borate) chloride acetonitrile disolvate
title_fullStr Di-μ-oxido-bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)dimangan­ese(III,IV)] bis­(tetra­phenyl­borate) chloride acetonitrile disolvate
title_full_unstemmed Di-μ-oxido-bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)dimangan­ese(III,IV)] bis­(tetra­phenyl­borate) chloride acetonitrile disolvate
title_short Di-μ-oxido-bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)dimangan­ese(III,IV)] bis­(tetra­phenyl­borate) chloride acetonitrile disolvate
title_sort di-μ-oxido-bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) n,n′,n′′,n′′′)dimangan­ese(iii,iv)] bis­(tetra­phenyl­borate) chloride acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151985/
https://www.ncbi.nlm.nih.gov/pubmed/21836836
http://dx.doi.org/10.1107/S1600536811019829
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AT boycedavidw dimoxidobis14811tetraazacyclotetradecanek4nnnndimanganeseiiiivbistetraphenylboratechlorideacetonitriledisolvate
AT brialaurene dimoxidobis14811tetraazacyclotetradecanek4nnnndimanganeseiiiivbistetraphenylboratechlorideacetonitriledisolvate