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Bis(μ-methano­lato-κ(2) O:O)bis­{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-yl­idene-κO)benzohydrazidato-κ(2) N′,O]oxido­vanadium(V)}

The dinuclear compound, [V(2)(C(12)H(11)BrN(2)O(2))(2)(CH(3)O)(2)O(2)], lies on a center of inversion. The doubly-deprotonated Schiff base O,N,O′-chelates to the V(V) atom; two metal atoms are bridged by the methoxide units. The coordination geometry is a distorted octa­hedron. Weak inter­molecular...

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Detalles Bibliográficos
Autores principales: Wong, Hon Wee, Lo, Kong Mun, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152071/
https://www.ncbi.nlm.nih.gov/pubmed/21836890
http://dx.doi.org/10.1107/S1600536811021647