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Bis(μ-methanolato-κ(2) O:O)bis{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-ylidene-κO)benzohydrazidato-κ(2) N′,O]oxidovanadium(V)}
The dinuclear compound, [V(2)(C(12)H(11)BrN(2)O(2))(2)(CH(3)O)(2)O(2)], lies on a center of inversion. The doubly-deprotonated Schiff base O,N,O′-chelates to the V(V) atom; two metal atoms are bridged by the methoxide units. The coordination geometry is a distorted octahedron. Weak intermolecular...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152071/ https://www.ncbi.nlm.nih.gov/pubmed/21836890 http://dx.doi.org/10.1107/S1600536811021647 |
| _version_ | 1782209720704040960 |
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| author | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
| author_facet | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
| author_sort | Wong, Hon Wee |
| collection | PubMed |
| description | The dinuclear compound, [V(2)(C(12)H(11)BrN(2)O(2))(2)(CH(3)O)(2)O(2)], lies on a center of inversion. The doubly-deprotonated Schiff base O,N,O′-chelates to the V(V) atom; two metal atoms are bridged by the methoxide units. The coordination geometry is a distorted octahedron. Weak intermolecular C—H⋯N hydrogen bonding is present in the crystal structure. The bromophenyl unit is disordered over two positions, with the major component being in a 0.909 (6) proportion. |
| format | Online Article Text |
| id | pubmed-3152071 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31520712011-08-11 Bis(μ-methanolato-κ(2) O:O)bis{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-ylidene-κO)benzohydrazidato-κ(2) N′,O]oxidovanadium(V)} Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear compound, [V(2)(C(12)H(11)BrN(2)O(2))(2)(CH(3)O)(2)O(2)], lies on a center of inversion. The doubly-deprotonated Schiff base O,N,O′-chelates to the V(V) atom; two metal atoms are bridged by the methoxide units. The coordination geometry is a distorted octahedron. Weak intermolecular C—H⋯N hydrogen bonding is present in the crystal structure. The bromophenyl unit is disordered over two positions, with the major component being in a 0.909 (6) proportion. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152071/ /pubmed/21836890 http://dx.doi.org/10.1107/S1600536811021647 Text en © Wong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng Bis(μ-methanolato-κ(2) O:O)bis{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-ylidene-κO)benzohydrazidato-κ(2) N′,O]oxidovanadium(V)} |
| title | Bis(μ-methanolato-κ(2)
O:O)bis{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-ylidene-κO)benzohydrazidato-κ(2)
N′,O]oxidovanadium(V)} |
| title_full | Bis(μ-methanolato-κ(2)
O:O)bis{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-ylidene-κO)benzohydrazidato-κ(2)
N′,O]oxidovanadium(V)} |
| title_fullStr | Bis(μ-methanolato-κ(2)
O:O)bis{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-ylidene-κO)benzohydrazidato-κ(2)
N′,O]oxidovanadium(V)} |
| title_full_unstemmed | Bis(μ-methanolato-κ(2)
O:O)bis{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-ylidene-κO)benzohydrazidato-κ(2)
N′,O]oxidovanadium(V)} |
| title_short | Bis(μ-methanolato-κ(2)
O:O)bis{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-ylidene-κO)benzohydrazidato-κ(2)
N′,O]oxidovanadium(V)} |
| title_sort | bis(μ-methanolato-κ(2)
o:o)bis{[4-bromo-n′-(1-methyl-3-oxidobut-2-en-1-ylidene-κo)benzohydrazidato-κ(2)
n′,o]oxidovanadium(v)} |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152071/ https://www.ncbi.nlm.nih.gov/pubmed/21836890 http://dx.doi.org/10.1107/S1600536811021647 |
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