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Thermodynamics and Kinetics of Sulfide Oxidation by Oxygen: A Look at Inorganically Controlled Reactions and Biologically Mediated Processes in the Environment

The thermodynamics for the first electron transfer step for sulfide and oxygen indicates that the reaction is unfavorable as unstable superoxide and bisulfide radical ions would need to be produced. However, a two-electron transfer is favorable as stable S(0) and peroxide would be formed, but the pa...

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Detalles Bibliográficos
Autores principales: Luther, George W., Findlay, Alyssa J., MacDonald, Daniel J., Owings, Shannon M., Hanson, Thomas E., Beinart, Roxanne A., Girguis, Peter R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Research Foundation 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3153037/
https://www.ncbi.nlm.nih.gov/pubmed/21833317
http://dx.doi.org/10.3389/fmicb.2011.00062