Cargando…
A Stereoselective Inverting sec-Alkylsulfatase for the Deracemization of sec-Alcohols
[Image: see text] A metallo-β-lactamase-type alkylsulfatase was found to catalyze the enantioselective hydrolysis of sec-alkylsulfates with strict inversion of configuration. This catalytic event, which does not have an analog in chemocatalysis, yields homochiral (S)-configurated alcohols and nonrea...
Autores principales: | , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2011
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3155277/ https://www.ncbi.nlm.nih.gov/pubmed/21770430 http://dx.doi.org/10.1021/ol201635y |