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Triazole–Au(I) complex as chemoselective catalyst in promoting propargyl ester rearrangements
Triazole–Au (TA–Au) catalysts were employed in several transformations involving propargyl ester rearrangement. Good chemoselectivity was observed, which allowed the effective activation of the alkyne without affecting the reactivity of the allene ester intermediates. These results led to the invest...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3167893/ https://www.ncbi.nlm.nih.gov/pubmed/21915202 http://dx.doi.org/10.3762/bjoc.7.115 |