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Triazole–Au(I) complex as chemoselective catalyst in promoting propargyl ester rearrangements

Triazole–Au (TA–Au) catalysts were employed in several transformations involving propargyl ester rearrangement. Good chemoselectivity was observed, which allowed the effective activation of the alkyne without affecting the reactivity of the allene ester intermediates. These results led to the invest...

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Detalles Bibliográficos
Autores principales: Wang, Dawei, Zhang, Yanwei, Cai, Rong, Shi, Xiaodong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3167893/
https://www.ncbi.nlm.nih.gov/pubmed/21915202
http://dx.doi.org/10.3762/bjoc.7.115