Asymmetric Au-catalyzed cycloisomerization of 1,6-enynes: An entry to bicyclo[4.1.0]heptene

A comprehensive study on the asymmetric gold-catalyzed cycloisomerization reaction of heteroatom tethered 1,6-enynes is described. The cycloisomerization reactions were conducted in the presence of the chiral cationic Au(I) catalyst consisting of (R)-4-MeO-3,5-(t-Bu)(2)-MeOBIPHEP-(AuCl)(2) complex a...

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Detalles Bibliográficos
Autores principales: Pradal, Alexandre, Chao, Chung-Meng, Toullec, Patrick Y, Michelet, Véronique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3169187/
https://www.ncbi.nlm.nih.gov/pubmed/21915203
http://dx.doi.org/10.3762/bjoc.7.116

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3169187/
https://www.ncbi.nlm.nih.gov/pubmed/21915203
http://dx.doi.org/10.3762/bjoc.7.116

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