Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

Previously we reported that direct zincation of N,N-dimethylaniline by the mixed-metal zincate reagent 1 ((TMEDA)Na(TMP)(t-Bu)Zn(t-Bu)) surprisingly led to meta-metallation (zincation) of the aniline, as manifested in the crystalline complex 2 ((TMEDA)Na(TMP)(m-C(6)H(4)-NMe(2))Zn(t-Bu)), and that io...

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Detalles Bibliográficos
Autores principales: Armstrong, David R, Balloch, Liam, Hevia, Eva, Kennedy, Alan R, Mulvey, Robert E, O'Hara, Charles T, Robertson, Stuart D
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3182433/
https://www.ncbi.nlm.nih.gov/pubmed/21977208
http://dx.doi.org/10.3762/bjoc.7.144

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3182433/
https://www.ncbi.nlm.nih.gov/pubmed/21977208
http://dx.doi.org/10.3762/bjoc.7.144

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