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Bromine–lithium exchange: An efficient tool in the modular construction of biaryl ligands

Regioselective bromine–lithium exchange reactions on polybrominated biaryls enable the modular synthesis of various polysubstituted biphenyls such as bis(dialkylphosphino)-, bis(diarylphosphino)- and dialkyl(diaryl)phosphinobiphenyls. All permutations of substituents at the ortho positions of the bi...

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Detalles Bibliográficos
Autores principales: Bonnafoux, Laurence, Leroux, Frédéric R, Colobert, Françoise
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3182437/
https://www.ncbi.nlm.nih.gov/pubmed/21977212
http://dx.doi.org/10.3762/bjoc.7.148